Effect of Annealing Temperature on Electrodeposited Iron Oxide Thin Films for Supercapacitor Study
DOI:
https://doi.org/10.32628/IJSRST25125504Keywords:
Iron oxide (Fe2O3), porous, Electrodeposition, Energy and powerAbstract
Fe2O3 samples were electrodeposited onto stainless steel at 1.4 V optimum potential using a 0.2 M FeCl3 precursor solution. They were then annealed at various annealing temperatures between 673 and 723 K with 50° increments. XRD analysis verifies that a crystalline rhombohedral crystal structure has formed. A consistent porous, spongy, beautiful gold flower-like morphology is demonstrated by the FESEM and HRTEM morphologies, and wettability tests indicate its hydrophilic nature. The 1 M KOH electrolyte was used for all electrochemical characterizations of the electrodes as they were deposited. The maximal specific capacitance of the optimized electrode is 898.52 Fg-1 at 2 mVs-1 . Using the galvanostatic charge-discharge technique, the highest values of specific energy (SE), specific power (SP), and columbic efficiency (ɳ) were determined to be 45.88 WhKg-1 , 5.33 KWKg-1 , and 97.67%,respectively. According to EIS investigations, the internal resistance was 0.7869 Ώ.
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G.T. Chavan, A. Sikora, R.C. Pawar, J. Warycha, P.J. Morankar, Chan-Wook Jeon, Hierarchical framework of CoZnS as a highperformance electrode material for supercapacitors, Ceramics International, 49, 1, (2023), 282-293, https://doi.org/10.1016/j.ceramint.2022.08.342. DOI: https://doi.org/10.1016/j.ceramint.2022.08.342
Ganesh T. Chavan, Pritam J. Morankar, Namita A. Ahir, Aviraj M. Teli, P. Rosaiah, Bilal Ahmed, Asad Syed, Abdallah M. Elgorban, Jinsung An, Chan-Wook Jeon, Synthesis of multinary composite (NiMnCuCoS) electrodes: Aqueous hybrid supercapacitors, Journal of Alloys and Compounds, 968, (2023), 171966, https://doi.org/10.1016/j.jallcom.2023.171966. DOI: https://doi.org/10.1016/j.jallcom.2023.171966
R. Lakshmana Naik, T. Bala Narsaiah, P. Justin, A. Naveen Kumar, M.N. Somashekar, N. Raghavendra, C.R. Ravikumar, Afaq Ahmad Khan, M.S. Santosh, Hydrothermally synthesized cobalt vanadate nanoparticles for photocatalytic degradation of Fast Orange Red dye and supercapacitor applications, Materials Science and Engineering: B, Volume 298, (2023), 116861, https://doi.org/10.1016/j.mseb.2023.116861. DOI: https://doi.org/10.1016/j.mseb.2023.116861
Sha Yi, Lei Wang, Xiong Zhang, Chen Li, Wenjie Liu, Kai Wang, Xianzhong Sun, Yanan Xu, Zhanxu Yang, Yu Cao, Jie Sun, Yanwei Ma, Cationic intermediates assisted selfassembly two-dimensional Ti3C2Tx/rGO hybrid nanoflakes for advanced lithium-ion capacitors, Science Bulletin, 66, 9, (2021), 914- 924, https://doi.org/10.1016/j.scib.2020.12.026. DOI: https://doi.org/10.1016/j.scib.2020.12.026
Moo Young Jung, Hyobeen Cho, Chanyong Lee, Yong Ju Yun, Suresh Kannan Balasingam, Yongseok Jun, Synergetic effect of a batterylike nickel phosphide and a pseudocapacitive cobalt phosphide electrodes for enhanced energy storage, Journal of Energy Storage, 66, (2023), 107321, https://doi.org/10.1016/j.est.2023.107321. DOI: https://doi.org/10.1016/j.est.2023.107321
Xiaokun Wang, Chen Hao, Jinsong Zhang, Chenghao Ni, Xiaohong Wang, Yutang Shen, Reasonable design and synthesis of nickel manganese sulfide nanoparticles derived from metal organic frameworks as electrode materials for supercapacitors, Journal of Power Sources, 539, (2022), 231594, https://doi.org/10.1016/j.jpowsour.2022.231594. DOI: https://doi.org/10.1016/j.jpowsour.2022.231594
Zhong, Cheng & Yida, Deng & Hu, Wenbin & Qiao, Jinli & Zhang, Lei & Zhang, Jiujun, A review of electrolyte materials and compositions for electrochemical supercapacitors. Chemical Society reviews, 44, (2015), 7431-7920, https://doi.org/10.1039/c5cs00303b. DOI: https://doi.org/10.1039/C5CS00303B
Shixiong Zhai, Zhuizhui Fan, Kaili Jin, Man Zhou, Hong Zhao, Yaping Zhao, Fengyan Ge, Xiaoyan Li, Zaisheng Cai, Synthesis of zinc sulfide/copper sulfide/porous carbonized cotton nanocomposites for flexible supercapacitor and recyclable photocatalysis with high performance, Journal of Colloid and Interface Science, 575, (2020), 306-316, https://doi.org/10.1016/j.jcis.2020.04.073. DOI: https://doi.org/10.1016/j.jcis.2020.04.073
C.D. Lokhande, D.P. Dubal, Oh-Shim Joo, Metal oxide thin film based supercapacitors, Current Applied Physics, 11, 3, (2011), 255- 270, https://doi.org/10.1016/j.cap.2010.12.001. DOI: https://doi.org/10.1016/j.cap.2010.12.001
Zeyuan Hu, Yidong Miao, Xiaolan Xue, Bin Xiao, Jiqiu Qi, Fuxiang Wei, Qinkun Meng, Yanwei Sui, Zhi Sun, Jinlong Liu, CuO@NiCoFe-S core–shell nanorod arrays based on Cu foam for high performance energy storage, Journal of Colloid and Interface Science, 599, (2021), 34-45, https://doi.org/10.1016/j.jcis.2021.04.085. DOI: https://doi.org/10.1016/j.jcis.2021.04.085
Divya Meena, Rinku Kumar, Saurabh Gupta, Obeidullah Khan, Deepak Gupta, Milan Singh,Energy storage in the 21st century: A comprehensive review on factors enhancing the next-generation supercapacitor mechanisms,Journal of Energy Storage, 72, C, (2023),109323, https://doi.org/10.1016/j.est.2023.109323. DOI: https://doi.org/10.1016/j.est.2023.109323
Robert de Levie, Andrew Vogt,A simple model for desorption transients,Journal of Electroanalytical Chemistry,341, 1–2, (1992),353-360,https://doi.org/10.1016/0022- 0728(92)80493-N. DOI: https://doi.org/10.1016/0022-0728(92)80493-N
Sharma, Swati & Chand, Prakash, Supercapacitor and Electrochemical Techniques: A Brief Review. Results in Chemistry, 5, (2023), 100885. https://doi.org/10.1016/j.rechem.2023.100885. DOI: https://doi.org/10.1016/j.rechem.2023.100885
Reenu, Sonia, Lakshita Phor, Ashok Kumar, Surjeet Chahal,Electrode materials for supercapacitors: A comprehensive review of advancements and performance,Journal of Energy Storage, 84, B, (2024),110698, https://doi.org/10.1016/j.est.202 4.110698. DOI: https://doi.org/10.1016/j.est.2024.110698
Kumar, N.; Kim, S.-B.; Lee, S.-Y.; Park, S.-J. Recent Advanced Supercapacitor: A Review of Storage Mechanisms, Electrode Materials, Modification, and Perspectives. Nanomaterials, 12, (2022) 3708. https://doi.org/10.3390/nano12203708. DOI: https://doi.org/10.3390/nano12203708
Anamika Banerjee, Biswajit Mondal, Anuradha Verma, Vibha R. Satsangi, Rohit Shrivastav, Abhishek Dey, Sahab Dass,Enhancing efficiency of Fe2O3 for robust and proficient solar water splitting using a highly dispersed bioinspired catalyst,Journal of Catalysis,352, (2017),83- 92,https://doi.org/10.1016/j.jcat.2017.04.023. DOI: https://doi.org/10.1016/j.jcat.2017.04.023
Durga Devi Suppiah, Nurhidayatullaili Muhd Julkapli, Suresh Sagadevan, Mohd Rafie Johan,Eco-friendly green synthesis approach and evaluation of environmental and biological applications of iron oxide nanoparticles,Inorganic Chemistry Communications,152, (2023),110700,https://doi.org/10.1016/j.inoche. 2023.110700. DOI: https://doi.org/10.1016/j.inoche.2023.110700
N.S. Mohan, R. Gokulkumar, J. Shankar, R. Sridharan, B. Logesh, R. Sasikumar, K. Vallarasu, V. Vijayalakshmi,A facile green approach of Fe2O3, Fe2O3 @Ag, Fe2O3 @AC and Fe2O3 @Ag@AC NPs synthesized via Cocos nucifera L for waste water treatment applications,Results in Chemistry,4, (2022),100626,https://doi.org/10.1016/j.rechem .2022.100626. DOI: https://doi.org/10.1016/j.rechem.2022.100626
Tadic, M., Trpkov, D., Kopanja, L., Vojnovic, S. and Panjan, M., "Hydrothermal synthesis of hematite (α-Fe2O3) nanoparticle forms: Synthesis conditions, structure, particle shape analysis, cytotoxicity and magnetic properties", Journal of Alloys and Compounds, 792, (2019), 599-609, http://dx.doi.org/10.1016/j.jallcom.2019.03.414 DOI: https://doi.org/10.1016/j.jallcom.2019.03.414
Y. Liu, S.P. Jiang, Z. Shao,Intercalation pseudocapacitance in electrochemical energy storage: recent advances in fundamental understanding and materials development,Materials Today Advances, 7, (2020),100072,https://doi.org/10.1016/j.mtadv. 2020.100072. DOI: https://doi.org/10.1016/j.mtadv.2020.100072
B. Y. Fugare, B. J. Lokhande, Study on structural, morphological, electrochemical and corrosion properties of mesoporous RuO2 thin films prepared by ultrasonic spray pyrolysis for supercapacitor electrode application, Mater. Sci. Semicond. Process., 71, (2017), 121-127, http://dx.doi.org/10.1016/j.mssp.2017.07.016. DOI: https://doi.org/10.1016/j.mssp.2017.07.016
Mingjiang Xie, Rui Xiao, Yi Yu, Yan Zhang, Cheng Du, Liu Wan, Jian Chen, Superhydrophilicity and ultrahigh-rate supercapacitor performances enabled by mesoporous carbon doped with conjugated hydroxyl, Journal of Energy Storage, 43, (2021), 103296,https://doi.org/10.1016/j.est.2021.1032 96. DOI: https://doi.org/10.1016/j.est.2021.103296
Bingjun Zhang, Kaustubh Rane, Mohammad Piri, Lamia Goual,Impact of surface roughness, surface charge, and temperature on sandstone wettability alteration by nanoparticles,Petroleum Science,20, 5, (2023),28522863,https://doi.org/10.1016/j.petsc i.2023.04.004. DOI: https://doi.org/10.1016/j.petsci.2023.04.004
Chakraborty AR, Zohora Toma FT, Alam K, Yousuf SB, Hossain KS. Influence of annealing temperature on Fe₂O₃ nanoparticles: Synthesis optimization and structural, optical, morphological, and magnetic properties characterization for advanced technological applications, Heliyon, 31, 10(21) (2024), e40000, doi: 10.1016/j.heliyon.2024.e40000. DOI: https://doi.org/10.1016/j.heliyon.2024.e40000
Diaa Eldin Fouad, Chunhong Zhang, Hamdy El-Didamony, Liu Yingnan, Tadele Daniel Mekuria, Ahmer Hussain Shah,Improved size, morphology and crystallinity of hematite (α-Fe2O3) nanoparticles synthesized via the precipitation route using ferric sulfate precursor,Results in Physics,12, (2019),12531,https://doi.org/10.1016/j.rinp.201 9.01.005 DOI: https://doi.org/10.1016/j.rinp.2019.01.005
R.S. Ingole, B. J. Lokhande, Ultrahigh specific capacitance of spray deposited nanoporous interconnected ruthenium oxide electrode fabric for supercharged capacitor, J. of Mater. Sci: Mater. Electron., 28, (2), (2017), 16374–16383, doi//10.1007/s10854-017-75484. DOI: https://doi.org/10.1007/s10854-017-7548-4
Lee, Hae-Min & Lee, Kangtaek & Kim, Chang-Koo, Electrodeposition of ManganeseNickel Oxide Films on a Graphite Sheet for Electrochemical Capacitor Applications, Materials, 7, (2014), 265-274, https://doi.org/10.3390/ma7010265. DOI: https://doi.org/10.3390/ma7010265
B.J. Lokhande, R.C. Ambare, R.S. Mane, S.R. Bharadwaj,Boron-doped cadmium oxide composite structures and their electrochemical measurements,Materials Research Bulletin,48, 8,(2013),29782983,https://doi.org/10.1016/j.ma terresbull.2013.03.028. DOI: https://doi.org/10.1016/j.materresbull.2013.03.028
Umer Shahzad, Hadi M. Marwani, Mohsin Saeed, Abdullah M. Asiri, Raed H. Althomali, Mohammed M. Rahman, Exploration of porous metal-organic frameworks (MOFs) for an efficient energy storage applications, Journal of Energy Storage, 74, (2023), 109518, https://doi.org/10.1016/j.est.2023.109518. DOI: https://doi.org/10.1016/j.est.2023.109518
Sarita Yadav, Ambika Sharma, Importance and challenges of hydrothermal technique for synthesis of transition metal oxides and composites as supercapacitor electrode materials, Journal of Energy Storage,44, (A), (2021),103295,https://doi.org/10.1016/j.est.202 1.103295. DOI: https://doi.org/10.1016/j.est.2021.103295
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